How Did Clausius Define Entropy?
Clausius, one of the main founders of the modern thermodynamics, is the originator of the term “entropy,” but before this coinage he used an expression “equivalence value of transformations” instead. The term “entropy,” which is now used as a physical term, was originally economically conceived as equivalent value of exchange. Thermodynamics itself was a field of physics that was economically motivated to improve the thermal efficiency of heat engines. So, it was half physics and half economics. Apart from Clausius’s interest, the term has now become an important keyword for solving the environment and resource problems.
What Work Does the Earth Do as a Heat Engine?
A heat engine is a device that repeatedly converts thermal energy into kinetic energy. It needs the difference of temperature and a working substance with a high rate of expansion to do useful work for us. It can be done in two ways: utilizing the change of volume of the working substance that hot and cold reservoirs make alternately expand or compress, and utilizing convection that the change of density resulting from the change of volume causes. A heat engine is not confined to an artificial one. The Earth also does useful work for living systems as a heat engine. The heat engine whose hot reservoir is solar radiation heat maintains the circulation of air and water, while the heat engine whose hot reservoir is geothermal heat maintains the circulation of mantle and mineral nutrition.